REACTION OF 1,1-DICYANO-2,2-BIS(TRIFLUOROMETHYL) ETHYLENE WITH ARYLAMINES

被引：19

作者：

KOMAROV, KV ^{[1
]}

CHKANIKOV, ND ^{[1
]}

GALAKHOV, MV ^{[1
]}

KOLOMIETZ, AF ^{[1
]}

FOKIN, AV ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST ORGANOELEMENTAL CPDS,MOSCOW 117813,RUSSIA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 47卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)80447-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have studied the nature and determined the application boundaries of C-alkylation of various arylamines and their derivatives with 1,1-dicyano-2,2-bis(trifluoromethyl)ethylene. The possibility of formation in these reactions of heterocyclic vicinal enaminonitriles has been shown. It has been found that in certain cases the reactions owe their complexity to oxidation- reduction process in which the electrophilic alkene plays the role of dehydrogenation agent. © 1990.

引用

页码：59 / 69

页数：11

共 9 条

[1]

CHKANIKOV ND, 1989, IZV AKAD NAUK SSSR K, P126

[2]

EMSLEY JW, 1966, HIGH RESOLUTION NUCL, V2, P46

[3] PERHALO KETONES .6. AROMATIC AMINO DERIVATIVES OF PERHALOACETONES [J].

GILBERT, EE ;

JONES, ES ;

SIBILIA, JP .

JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (04) :1001-&

[4]

KOMAROV KV, 1988, IAN SSSR KH, P1920

[5]

KOMAROV KV, 1988, IAN SSSR KH, P1917

[6]

KOMAROV KV, 1988, IAN SSSR KH, P2417

[7] FLUORINE-CONTAINING 1,1-DICYANOETHYLENES - THEIR PREPARATION, DIELS-ALDER REACTIONS, AND DERIVED NORBORNENES AND NORBORNANES [J].

MIDDLETON, WJ ;

BINGHAM, EM .

JOURNAL OF FLUORINE CHEMISTRY, 1982, 20 (03) :397-418

[8]

MIDDLETON WJ, 1965, J ORG CHEM, V30, P1420

[9]

ZELENIN AE, 1986, IAN SSSR KH, P2080

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