ZIRCONIUM CHEMISTRY INVOLVING BENZAMIDINATE LIGANDS - REDUCTION OF [PHC(NSIME(3))(2)]2ZRCL2 TO FORM AN IMIDO-IMINOACYL COMPOUND BY CARBON-NITROGEN BOND-CLEAVAGE

被引：67

作者：

HAGADORN, JR ^{[1
]}

ARNOLD, J ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 12期

关键词：

D O I：

10.1021/om00024a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A range of zirconium(IV) derivatives with N,N'-bis(trimethylsilyl)benzamidinate ligands has been prepared with [PhC(NSiMe(3))(2)]2ZrCl2 as the starting material. Reduction of the dichloride in, the presence of excess diphenylacetylene gave [PhCN(SiMe(3))(2)]Zr-2(eta(2)-C-4-Ph(4)). In, the absence of acetylene, orange crystals of the mu-imido-eta(2)-iminoacyl species {[PhCN(SiMe(3))(2)]Zr(eta(2)-Ph-CNSiMe(3))(mu-NSiMe(3))}(2) were obtained.

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页码：4670 / 4672

页数：3

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