ORGANOMETALLIC ACTINIDE COMPOUNDS - SYNTHESES AND APPLICATIONS TO HOMOGENEOUS CATALYSIS

被引：2

作者：

FOLCHER, G

机构：

[1] CNRS-CEA, Gif-sur-Yvette, Fr, CNRS-CEA, Gif-sur-Yvette, Fr

来源：

JOURNAL OF THE LESS-COMMON METALS | 1986年 / 122卷

关键词：

HOMOGENEOUS CATALYSIS - PHYSICOCHEMICAL PROPERTIES;

D O I：

10.1016/0022-5088(86)90402-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Organometallic chemistry of the actinides has been developed over the last 20 years. Many compounds with PI ligands such as C//5H//5** minus or C//8H//8**″ ** minus can be synthesized from thorium to californium. In the cases of thorium and uranium the An-C sigma bond can be stabilized. These compounds exhibit different physicochemical properties from those of their d series analogues. Electronic, NMR, EPR and Mossbauer spectroscopy studies as well as magnetic measurement establish the role of f electrons in stabilizing the structure and activity of the compounds and allow comparison with organometallic derivatives of the lanthanides.

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页码：139 / 151

页数：13

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