Cy2NH2NO3SnBu2Cl2 center dot H2O AND Cy2NH2NO3SnPh2Cl2 center dot 2H2O: SYNTHESIS AND INFRARED STUDY

被引:0
作者
Mbaye, Abdou [1 ]
Diop, Cheikh Abdoul Khadir [1 ]
Diop, Libasse [1 ]
机构
[1] Univ Cheikh Anta Diop, Fac Sci & Tech, Dept Chim, Lab Chim Minerale & Analyt, Dakar, Senegal
关键词
discrete structures; monocoordinating O-3(-); SnR2; residue; suppramolecular architectures;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
On allowing Cy2NH2NO3 to react with SnBu2Cl2 and SnPh2Cl2, the two studied adducts were obtained. While considering the complex-anions [SnBu2Cl2NO3.H2O](-) and [NO3.SnPh2Cl2 H2O](-),discrete structures were suggested with monocoordinating nitrate and octahedral environment around the tin centre. When the cation is involved through N-H----O or N-H----Cl hydrogen bonds, suppramolecular architectures are obtained.
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页码:275 / 278
页数:4
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