INTRAMOLECULAR HYDROGEN-BONDS IN QUADRICYCLANE DERIVATIVES

被引：0

作者：

IRNGARTINGER, H

JAHN, R

机构：

来源：

CROATICA CHEMICA ACTA | 1991年 / 64卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two bulky hydroxy-isopropyl substituents on the quadricyclane 2 generate a compression of the intramolecular hydrogen bond (014...015 2.687 angstrom) and a lengthening of the C1-C5 bond (1.573 angstrom) of the four membered ring. The corresponding values of the bis(hydroxymethyl) derivative 1 are 010...011 2.799 angstrom and C1-C5 1.546 angstrom), respectively.

引用

页码：289 / 294

页数：6