SYNTHESIS AND STRUCTURE OF A 5-COORDINATE TRIARYLGALLIUM COMPLEX

被引：19

作者：

COGGIN, DAK

FANWICK, PE

GREEN, MA

机构：

[1] PURDUE UNIV,DEPT MED CHEM,DIV NUCL PHARM,W LAFAYETTE,IN 47907

[2] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 14期

关键词：

D O I：

10.1039/c39930001127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The neutral gallium(III) compounds L3Ga, L2GaCl and [L2GaOH]2 (L = -C6H4-o-CH2NMe2) are synthesized and shown by X-ray crystallographic analysis to adopt trigonal bipyramidal coordination geometries; L3Ga is the first example of a five-coordinate triorganogallium(III) complex.

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页码：1127 / 1129

页数：3

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