STRUCTURES AND PROPERTIES OF [CU4(C3X5)3]2- (X = S AND SE) CLUSTER ANION COMPLEXES

被引：4
|
作者：
MATSUBAYASHI, GE
机构：
[1] Institute of Chemistry, College of General Education, Osaka University, Toyonaka
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1992年 / 67卷 / 1-4期
关键词：
D O I：
10.1080/10426509208045856
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[CiMCgXgJg]2“(X = S and Se) [CgS52‘= 4, 5-dimercapto-l, 3-dithlole-2-thionate(2-) and CoSe^ = 4, 5-di-(hydroseleno)-l, 3-diselenole-2-selonate(2-)] cluster anion complexes were prepared. Molecular interactions among the anion moieties through S~S and Se-Se contacts in the solid state were deduced from X-ray structure analysis and electronic reflectance spectra. They reacted with [FeCp2]+and [FeCp2]+cations (Cp and Cp = the cyclopentadienyl and decamethylcyclopentadienyl anions, respectively) to give partially oxidized species with ligand-centered oxidation. They behave as semiconductors with electrical conductivities of lx(10“3-10-7) S cm-1 measured for the compacted pellets. © 1992, Taylor & Francis Group, LLC. All rights reserved.
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页码：339 / 344
页数：6
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