STRUCTURE, IONIC-CONDUCTIVITY, AND PHASE-TRANSFORMATION IN NEW POLYMORPHS OF THE DOUBLE CHLORIDE SPINEL, LI2FECL4

被引：25

作者：

KANNO, R ^{[1
]}

TAKEDA, Y ^{[1
]}

TAKAHASHI, A ^{[1
]}

YAMAMOTO, O ^{[1
]}

SUYAMA, R ^{[1
]}

KUME, S ^{[1
]}

机构：

[1] OSAKA UNIV,COLL GEN EDUC,TOYONAKA,OSAKA 560,JAPAN

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1988年 / 72卷 / 02期

关键词：

CRYSTALS - Structure - HEAT TREATMENT - Annealing - SOLIDS - Phase Transitions;

D O I：

10.1016/0022-4596(88)90040-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The purpose of this investigation is to obtain more insight into the iron spinel. We first assumed, and later were able to prove, the existence of a low-temperature iron spinel modification. The structure of the new low-temperature modification was determined by X-ray powder Rietveld analysis. The ionic conductivity of both the orthorhombic and cubic spinels was examined and compared. The phase diagram near the spinel formation domain was also studied.

引用

页码：363 / 375

页数：13

共 16 条

[1] STRUCTURE, IONIC MOTION AND CONDUCTIVITY IN SOME SOLID-SOLUTIONS OF THE LICL-MCL2 SYSTEMS (M = MG, V, MN)
CROS, C
HANEBALI, L
LATIE, L
VILLENEUVE, G
WANG, G
[J]. SOLID STATE IONICS, 1983, 9-10 (DEC) : 139 - 147
[2] HAGENMULLER P, 1978, SOLID ELECTROLYTES
[3] Izumi, 1985, J MINER SOC JAPAN, V17, P37
[4] PHASE-TRANSITION OF THE SOLID LITHIUM ION CONDUCTOR WITH THE SPINEL STRUCTURE - LI2-2XM1+XCL4 (M=MG,MN)
KANNO, R
TAKEDA, Y
YAMAMOTO, O
CROS, C
GANG, W
HAGENMULLER, P
[J]. SOLID STATE IONICS, 1986, 20 (02) : 99 - 103
[5] IONIC-CONDUCTIVITY AND PHASE-TRANSITION OF THE SPINEL SYSTEM LI2-2XM1+X CL4(M=MG,MN,CD)
KANNO, R
TAKEDA, Y
TAKADA, K
YAMAMOTO, O
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1984, 131 (03) : 469 - 474
[6] IONIC-CONDUCTIVITY AND STRUCTURE OF NEW DOUBLE CHLORIDE LI6FECL8 IN THE LICL-FECL2 SYSTEM
KANNO, R
TAKEDA, Y
MORI, M
YAMAMOTO, O
[J]. CHEMISTRY LETTERS, 1987, (07) : 1465 - 1468
[7] PHASE-DIAGRAM AND IONIC-CONDUCTIVITY OF THE LITHIUM-CHLORIDE IRON(II) CHLORIDE SYSTEM
KANNO, R
TAKEDA, Y
TAKADA, K
YAMAMOTO, O
[J]. SOLID STATE IONICS, 1983, 9-10 (DEC) : 153 - 156
[8] IONIC-CONDUCTIVITY OF SOLID LITHIUM ION CONDUCTORS WITH THE SPINEL STRUCTURE - LI2MCL4 (M = MG, MN, FE, CD)
KANNO, R
TAKEDA, Y
YAMAMOTO, O
[J]. MATERIALS RESEARCH BULLETIN, 1981, 16 (08) : 999 - 1005
[9] KANNO R, IN PRESS
[10] KANNO R, 1986, J ELECTROCHEM SOC, V133, P1053

← 1 2 →