ALTERATION OF THE REACTIVITY OF A TELLUROPHENE WITHIN A CORE-MODIFIED PORPHYRIN ENVIRONMENT - SYNTHESIS AND OXIDATION OF 21-TELLURAPORPHYRIN

被引：80

作者：

LATOSGRAZYNSKI, L ^{[1
]}

PACHOLSKA, E ^{[1
]}

CHMIELEWSKI, PJ ^{[1
]}

OLMSTEAD, MM ^{[1
]}

BALCH, AL ^{[1
]}

机构：

[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 20期

关键词：

OXIDATIONS; PORPHYRINOIDS; TELLURIUM COMPOUNDS;

D O I：

10.1002/anie.199522521

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A pyrrole ring of a porphyrin as an intramolecular proton donor: compound 1 (depicted below), with a deprotonated pyrrole ring, has been isolated as an intermediate in the oxidative transformation of the corresponding air‐sensitive 21‐telluraporphyrin into 21‐oxaporphyrin. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：2252 / 2254

页数：3

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