RRK MODEL OF UNIMOLECULAR SURFACE-REACTION

被引：4
|
作者：
SOLC, M
机构：
[1] Institute of Inorganic Chemistry, Czechoslovak Academy of Sciences, Pelléova24, 160 00
来源：
CATALYSIS LETTERS | 1993年 / 18卷 / 1-2期
关键词：
INTRAMOLECULAR ENERGY FLOW; SURFACE REACTION; RRK MODEL;
D O I：
10.1007/BF00769511
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
After the chemisorption of a polyatomic molecule on an active site of a catalyst, the adsorption energy is localized in the new, molecule-active site bond. Assuming the free flow of adsorption energy into the internal vibrations of the adsorbed molecules only, the Rice-Ramsperger-Kassel (RRK) statistical theory of a spontaneous decomposition can describe the surface reaction of these molecules. The mean vibrational energy of adsorbed molecules is determined by the temperature of reactants in the gas phase, and by the heat of adsorption.
引用
收藏
页码：177 / 182
页数：6
相关论文
共 50 条
  • [1] NOVEL SURFACE-REACTION MODEL IN DRY-ETCHING PROCESS SIMULATOR
    MISAKA, A
    HARAFUJI, K
    KUBOTA, M
    NOMURA, N
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1992, 31 (12B): : 4363 - 4369
  • [2] SURFACE-REACTION INDUCED BY MULTIPLY-CHARGED IONS
    MOCHIJI, K
    ITABASHI, N
    YAMAMOTO, S
    OCHIAI, I
    OKUNO, K
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1994, 33 (12B): : 7108 - 7111
  • [3] GAAS DRY ETCHING USING ELECTRON-BEAM INDUCED SURFACE-REACTION
    WATANABE, H
    MATSUI, S
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1991, 30 (11B): : 3190 - 3194
  • [4] DIAGNOSTICS OF HYDROGEN ROLE IN THE SI SURFACE-REACTION PROCESSES EMPLOYING INSITU FOURIER-TRANSFORM INFRARED-ATTENUATED TOTAL REFLECTION
    KAWAMURA, K
    ISHIZUKA, S
    SAKAUE, H
    HORIIKE, Y
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1991, 30 (11B): : 3215 - 3218
  • [5] Convection Effects in the BIAcore Dextran Layer: Surface Reaction Model
    David A. Edwards
    Bulletin of Mathematical Biology, 2006, 68
  • [6] Convection effects in the BIAcore dextran layer: Surface reaction model
    Edwards, DA
    BULLETIN OF MATHEMATICAL BIOLOGY, 2006, 68 (03) : 627 - 654
  • [7] Exploring surface reaction mechanism using a surface reaction neural network framework
    Luo, Lin
    Liu, Qimin
    Sun, Junhao
    Huang, Yaosong
    CHEMICAL ENGINEERING SCIENCE, 2025, 306
  • [8] Effects of surface reaction on gas phase reaction in micro channel
    Shao, Xia
    Pan, Jianfeng
    Tang, Aikun
    Hu, Song
    Hou, Zhiyong
    Nongye Jixie Xuebao/Transactions of the Chinese Society for Agricultural Machinery, 2015, 46 (12): : 391 - 396
  • [9] Chemisorption and Surface Reaction of Hafnium Precursors on the Hydroxylated Si(100) Surface
    Tai, Truong Ba
    Lim, Jonghun
    Shin, Hyeyoung
    COATINGS, 2023, 13 (12)
  • [10] A coupled seepage and dissolution model of rough rock fractures considering surface reaction based on lattice Boltzmann method
    Shen L.
    Wang Z.
    Zeng Y.
    Li Z.
    Li S.
    Yanshilixue Yu Gongcheng Xuebao/Chinese Journal of Rock Mechanics and Engineering, 2019, 38 (08): : 1615 - 1626
12345