PHOTOINITIATORS WITH FUNCTIONAL-GROUPS .1. POLYMER PHOTOINITIATORS

被引：21
|
作者：
KLOS, R
GRUBER, H
GREBER, G
机构：
[1] Institute of Chemical Technology of Organic Materials, Vienna University of Technology
来源：
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1991年 / A28卷 / 09期
关键词：
D O I：
10.1080/00222339108054070
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of new polymerizable photoinitiators (PIs) based on hydroxyalkylphenones has been synthesized by Grignard reaction of 4-vinylphenylmagnesiumchloride with suitable carbonyl compounds. Radical homopolymerization and copolymerization of the PIs with various vinyl monomers yielded polymer PIs compatible with either hydrophilic or hydrophobic resin systems. The PI monomers and polymers are characterized by excellent photoinitiating activity comparable with the most efficient known PIs and exhibit high migration stability.
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页码：925 / 947
页数：23
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