SYNTHESIS OF 1-SUBSTITUTED TRANS-2-THIAHYDRINDANES AND 3-SUBSTITUTED TRANS-2-THIADECALINS

被引：1

作者：

VOLYNSKII, NP

ALIKHANOVA, OL

机构：

[1] A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 08期

关键词：

D O I：

10.1007/BF01172271

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methods of synthesis of 1-R-trans-2-thiahydrindanes and 3-R-trans-2-thiadecalins from trans-1-methoxymethyl-2-chlorocyclohexane have been developed. The order of the chromatographic elution of the isomeric sulfides formed has been found. The configurations of the compounds have been established by H-1 and C-13 NMR spectroscopy. The characteristics of the intermediate and final compounds are given. The splitting of 1-R-trans-2-oxahydrindanes and 3-R-trans-2-oxadecalins by the PBr3/conc. HBr system has been effected.

引用

页码：1664 / 1671

页数：8

共 14 条

[1] CONFORMATIONAL-ANALYSIS OF THIOLANE RING-SYSTEM .1. STEREOCHEMISTRY OF BASE-CATALYZED H-D EXCHANGE, PYRAMIDAL INVERSION, AND PROTON MAGNETIC-RESONANCE SPECTRUM OF TRANS-3-METHYL-3-THIONIABICYCLO[4.3.0]NONANE IODIDE, A CONFORMATIONALLY RIGID THIOLANIUM CATION [J].