THE SYNTHESIS OF TRIPODAL NITROGEN DONOR LIGANDS AND THEIR CHARACTERIZATION AS PD(II)ME2 AND PD(III)ME DERIVATIVES

被引：75
作者：
BYERS, PK [1 ]
CANTY, AJ [1 ]
HONEYMAN, RT [1 ]
机构：
[1] UNIV TASMANIA,DEPT CHEM,HOBART,TAS 7001,AUSTRALIA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 385卷 / 03期
基金：
澳大利亚研究理事会;
关键词：
D O I：
10.1016/0022-328X(90)85013-O
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New tripod ligands containing pyridin-2-yl (py), N-methylimidazol-2-yl (mim), and pyrazol-1-yl (pz) groups have been made by addition of 2-bromopyridine to deprotonated (py)(mim)CH2 or (mim)2CH2 to form (py)2(mim)CH and (py) (mim)2CH, or by simple condensation reactions of (pz)2CO with (mim)CHO or (py)CHO to form (pz)2(mim)CH and (pz)2(py)CH. The ligands may have general application in coordination and organometallic chemistry, especially bis(pyrazol-1-yl)(pyridin-2-yl)methane [(pz)2(py)CH], which can be readily synthesized and is an unsymmetrical tripod closely related to (pz)3CH and (py)3CH. Dimethylpalladium(II) and methyl(iodo)palladium(II) complexes of the ligands have been isolated, and compared with complexes of (pz)3CH, (py)3CH, and (pz)4C. © 1990.
引用
收藏
页码：417 / 427
页数：11
相关论文
共 20 条
  • [1] CRYSTAL-STRUCTURE OF DIMETHYL-[TRIS(N-METHYLIMIDAZOL-2-YL)METHANOL-N,N']-GOLD(III) NITRATE
    BYERS, PK
    CANTY, AJ
    SKELTON, BW
    WHITE, AH
    [J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1985, 38 (08) : 1251 - 1255
  • [2] COORDINATION CHEMISTRY OF DIMETHYLGOLD(III) - SYNTHESIS, STRUCTURAL STUDIES, AND FLUXIONAL BEHAVIOR OF COMPLEXES WITH POLYDENTATE LIGANDS
    BYERS, PK
    CANTY, AJ
    MINCHIN, NJ
    PATRICK, JM
    SKELTON, BW
    WHITE, AH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (06): : 1183 - 1189
  • [3] METHYLPALLADIUM(II) COMPLEXES OF PYRAZOLE AND THIOETHER DONOR LIGANDS
    BYERS, PK
    CANTY, AJ
    [J]. INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 104 (01): : L13 - L14
  • [4] ORGANOPALLADIUM(IV) CHEMISTRY - OXIDATIVE ADDITION OF ORGANOHALIDES TO DIMETHYLPALLADIUM(II) COMPLEXES TO FORM ETHYL, SIGMA-BENZYL, AND SIGMA-ALLYLPALLADIUM(IV) COMPLEXES
    BYERS, PK
    CANTY, AJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (10) : 639 - 641
  • [5] SYNTHESIS OF THE 1ST ORGANOPALLADIUM(IV) CATIONS, INCLUDING THE 1ST X-RAY STUDY OF ISOSTRUCTURAL ORGANOPALLADIUM(IV) AND PLATINUM(IV) COMPLEXES, [FAC-MME3(TRIS(PYRAZOL-1-YL)METHANE-N,N',N'')]I
    BYERS, PK
    CANTY, AJ
    SKELTON, BW
    WHITE, AH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (14) : 1093 - 1095
  • [6] SYNTHESIS, SPECTROSCOPIC, AND STRUCTURAL STUDIES OF THE METHYLPALLADIUM(II) COMPLEXES [(PDME(SME2)X)2] (X = CL, BR, OR I) CRYSTAL-STRUCTURE OF TRANS-[(PDME(SME2)(MU-CL))2]
    BYERS, PK
    CANTY, AJ
    ENGELHARDT, LM
    WHITE, AH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (08): : 1731 - 1734
  • [7] BYERS PK, 1990, IN PRESS ORGANOMETAL, V9
  • [8] COORDINATION CHEMISTRY OF DIMETHYLGOLD(III) AND METHYLMERCURY(II) - SYNTHESIS, H-1-NMR AND STRUCTURAL STUDIES OF POLY(PYRAZOL-1-YL)BORATE COMPLEXES
    CANTY, AJ
    MINCHIN, NJ
    PATRICK, JM
    WHITE, AH
    [J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1983, 36 (06) : 1107 - 1113
  • [9] INTERACTION OF PALLADIUM(II) WITH POLYDENTATE LIGANDS, INCLUDING THE SYNTHESIS AND STRUCTURE OF BIS[TRIS(PYRAZOL-1-YL)BORATO-N,N']PALLADIUM(II) AND THE CATIONS [PD(L)2]2+ [L=TRIS(PYRAZOL-1-YL)METHANE-N,N' OR TRIS(PYRIDIN-2-YL)METHANE-N,N']
    CANTY, AJ
    MINCHIN, NJ
    ENGELHARDT, LM
    SKELTON, BW
    WHITE, AH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (03): : 645 - 650
  • [10] COORDINATION CHEMISTRY OF DIMETHYLGOLD(III) - SYNTHESIS, SPECTROSCOPIC, AND STRUCTURAL STUDIES OF COMPLEXES WITH NEUTRAL AROMATIC NITROGEN-DONOR LIGANDS
    CANTY, AJ
    MINCHIN, NJ
    HEALY, PC
    WHITE, AH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (09): : 1795 - 1802
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