SYNTHESIS, PHOTOPHYSICAL PROPERTIES AND DNA-BINDING STUDIES OF NOVEL LUMINESCENT RHENIUM(I) COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF [RE(DPPN)(CO)(3)(PY)](OTF)

被引：124

作者：

YAM, VWW ^{[1
]}

LO, KKW ^{[1
]}

CHEUNG, KK ^{[1
]}

KONG, RYC ^{[1
]}

机构：

[1] CITY UNIV HONG KONG, DEPT BIOL & CHEM, KOWLOON, HONG KONG

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 11期

关键词：

D O I：

10.1039/c39950001191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel luminescent rhenium(I) complexes, [Re(dppz)(CO)(3)(py)](OTf) 1 and [Re(dppn)(CO)(3)(py)](OTf) 2 are synthesized and their photophysical properties studied; X-ray structural studies of 2 reveal a highly planar dppn ligand which may account for the interaction of 1 and 2 with double-stranded calf thymus DNA.

引用

页码：1191 / 1193

页数：3

共 34 条

[1] NEW ALKYNYL-LINKED AND VINYL-LINKED BENZO-CROWN AND AZA-CROWN ETHER-BIPYRIDYL RUTHENIUM(II) COMPLEXES WHICH SPECTROCHEMICALLY RECOGNIZE GROUP-IA AND GROUP-IIA METAL-CATIONS [J].

BEER, PD ;

KOCIAN, O ;

MORTIMER, RJ ;

RIDGWAY, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (17) :2629-2638

[2] APPLICATION OF THE ENERGY-GAP LAW TO NONRADIATIVE, EXCITED-STATE DECAY [J].

CASPAR, JV ;

MEYER, TJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (06) :952-957

[3] PHOTOCHEMISTRY OF RU(BPY)32+ - SOLVENT EFFECTS [J].

CASPAR, JV ;

MEYER, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (17) :5583-5590

[4] DERIVATIVES OF 1,10-PHENANTHROLINE-5,6-QUINONE [J].

DICKESON, JE ;

SUMMERS, LA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1970, 23 (05) :1023-&

[5] MOLECULAR LIGHT SWITCH FOR DNA - RU(BPY)2(DPPZ)2+ [J].

FRIEDMAN, AE ;

CHAMBRON, JC ;

SAUVAGE, JP ;

TURRO, NJ ;

BARTON, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (12) :4960-4962

[6]

GIORDANO PJ, 1979, J AM CHEM SOC, V101, P2888, DOI 10.1021/ja00505a016

[7] [RUO(DPPZ)(TPY)]2+ - A DNA CLEAVAGE AGENT WITH HIGH DNA AFFINITY [J].

GUPTA, N ;

GROVER, N ;

NEYHART, GA ;

LIANG, WG ;

SINGH, P ;

THORP, HH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (08) :1048-1050

[8] NOVEL DIPYRIDOPHENAZINE COMPLEXES OF RUTHENIUM(II) - EXPLORING LUMINESCENT REPORTERS OF DNA [J].

HARTSHORN, RM ;

BARTON, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (15) :5919-5925

[9] PERCHLORATE AND DIFLUOROPHOSPHATE COORDINATION DERIVATIVES OF RHENIUM CARBONYL [J].

HORN, E ;

SNOW, MR .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1980, 33 (11) :2369-2376

[10]

Horvath O., 1993, CHARGE TRANSFER PHOT

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