THE CRYSTAL-STRUCTURE OF [TECL3(15-CROWN-5)]SBCL6

被引：5

作者：

SCHAFER, M ^{[1
]}

DEHNICKE, K ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,HANS MEERWEIN STR,W-3550 MARBURG,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 614卷 / 08期

关键词：

TRICHLORO(15-CROWN-6)TELLURIUM HEXACHLOROANTIMONATE; PREPARATION; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19926140805

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound is synthesized by the reaction of tellur tetrachloride, 15-crown-5 and antimony pentachloride in acetonitrile solution, forming colourless crystals, which were characterized by IR spectroscopy and an X-ray structure determination. Space group Pnma, Z = 4, 1 966 observed unique reflections, R = 0.072, R(w) = 0.052. The compound forms ions [TeCl3(15-crown-5)]+ and SbCl6-; in the cation the tellurium atom is eightfold coordinated by the three chlorine atoms and the five oxygen atoms of the crownether molecule (Te-O bond lengths 266 and 279 pm).

引用

页码：21 / 24

页数：4

共 50 条

[41] SYNTHESIS AND CRYSTAL-STRUCTURE OF HG5SB2I6
SHEVELKOV, AV
DIKAREV, EV
POPOVKIN, BA
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (02): : 389 - 392
[42] HALOGENO-NITROSYL COMPLEXES OF MOLYBDENUM AND TUNGSTEN - CRYSTAL-STRUCTURES OF [NA2(15-CROWN-5)2(CH3CN)][MOCL4(NO)2] AND [NA(15-CROWN-5)]2[MOF4CL(NO)]
RENTSCHLER, E
MASSA, W
VOGLER, S
DEHNICKE, K
FENSKE, D
BAUM, G
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1991, 592 (01): : 59 - 72
[43] Synthesis and Crystal Structure of Chiral Substituted (S)-2-[(4-Methoxyphenoxy) Methyl]-15-Crown-5 Ether with Sodium Perchlorate Complex
Nermin Doğan
Süheyla Özbey
Mehmet Karakaplan
Tarık Aral
Journal of Chemical Crystallography, 2008, 38 : 943 - 947
[44] Synthesis and Crystal Structure of Chiral Substituted (S)-2-[(4-Methoxyphenoxy) Methyl]-15-Crown-5 Ether with Sodium Perchlorate Complex
Dogan, Nermin
Ozbey, Sueheyla
Karakaplan, Mehmet
Aral, Tarik
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2008, 38 (12) : 943 - 947
[45] Halide abstraction as a route to cationic molybdenum(IV) compounds: Crystal and molecular structure of [CpMoCl(MeCN)(4)][SbCl6](2)center dot MeCN
Willey, GR
Woodman, TJ
Drew, MGB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 510 (1-2) : 213 - 217
[46] SYNTHESIS AND CRYSTAL-STRUCTURE OF [K(18-CROWN-6)]2S6.2CH3CN
BACHER, AD
MULLER, U
RUHLANDTSENGE, K
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1992, 47 (12): : 1673 - 1676
[47] CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF CE3PD6SB5
GORDON, RA
DISALVO, FJ
POTTGEN, R
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 228 (01) : 16 - 22
[48] ON THE CRYSTAL-STRUCTURE OF MNF3 AND MNPTF6
SCHROTTER, F
MULLER, BG
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (08): : 1426 - 1430
[49] Synthesis and crystal structure of [Se3N2Cl]+SbCl6-
Lau, C
Neumuller, B
Dehnicke, K
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (04): : 543 - 545
[50] SYNTHESES, FIR SPECTRA, AND CRYSTAL-STRUCTURES OF THE PENTASELENIDES K2SE5 AND [NA(15-CROWN-5)]2SE5
MULLER, V
FRENZEN, G
DEHNICKE, K
FENSKE, D
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1992, 47 (02): : 205 - 210

← 1 2 3 4 5 →