THE CRYSTAL-STRUCTURE OF [TECL3(15-CROWN-5)]SBCL6

被引：5

作者：

SCHAFER, M ^{[1
]}

DEHNICKE, K ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,HANS MEERWEIN STR,W-3550 MARBURG,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 614卷 / 08期

关键词：

TRICHLORO(15-CROWN-6)TELLURIUM HEXACHLOROANTIMONATE; PREPARATION; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19926140805

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound is synthesized by the reaction of tellur tetrachloride, 15-crown-5 and antimony pentachloride in acetonitrile solution, forming colourless crystals, which were characterized by IR spectroscopy and an X-ray structure determination. Space group Pnma, Z = 4, 1 966 observed unique reflections, R = 0.072, R(w) = 0.052. The compound forms ions [TeCl3(15-crown-5)]+ and SbCl6-; in the cation the tellurium atom is eightfold coordinated by the three chlorine atoms and the five oxygen atoms of the crownether molecule (Te-O bond lengths 266 and 279 pm).

引用

页码：21 / 24

页数：4

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