A PYROLYSIS JET SPECTROSCOPIC STUDY OF THE ROTATIONALLY RESOLVED ELECTRONIC-SPECTRUM OF DICHLOROCARBENE

被引：82
|
作者：
CLOUTHIER, DJ [1 ]
KAROLCZAK, J [1 ]
机构：
[1] ADAM MICKIEWICZ UNIV,INST PHYS,QUANTUM ELECTR LAB,PL-60780 POZNAN,POLAND
来源：
JOURNAL OF CHEMICAL PHYSICS | 1991年 / 94卷 / 01期
关键词：
D O I：
10.1063/1.460378
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The rotationally resolved, gas phase vibronic spectrum of dichlorocarbene has been recorded using the technique of pyrolysis jet spectroscopy. The rovibronic analysis has established the band origin of the A approximately 1B1-X approximately 1A1 electronic transition to be at 17 255.67 cm-1. The observed vibrational frequencies in the ground and excited states are very close to published values from matrix isolation data. The excited state structure has a 131.4-degrees CICCI angle and a 1.652 angstrom CCI bond length.
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页码：1 / 10
页数：10
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