TEMPLATE SYMMETRY EFFECT IN OPEN-FRAMEWORK SYNTHESIS - A NEW VANADIUM(IV) PHOSPHATE

被引：32

作者：

BU, XH ^{[1
]}

FENG, PY ^{[1
]}

STUCKY, GD ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 13期

关键词：

D O I：

10.1039/c39950001337

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The template symmetry effect in open-framework syntheses is demonstrated in a newly synthesized vanadium (IV) phosphate encapsulating organic piperazine dications; the hydrothermal synthesis and X-ray crystal structure are described; the structure adopted: suggests that inorganic,condensation around the organic molecules is dictated by the template molecular symmetry.

引用

页码：1337 / 1338

页数：2

共 6 条

[1] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[2] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE OCTAHEDRAL-TETRAHEDRAL FRAMEWORK INDIUM PHOSPHATE CS[IN-2(PO4)(HPO4)(2)(H2O)(2)] [J].

DHINGRA, SS ;

HAUSHALTER, RC .

JOURNAL OF SOLID STATE CHEMISTRY, 1994, 112 (01) :96-99

[3]

FENG P, UNPUB ANGEW CHEM

[4] HYDROTHERMAL SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE 2 NEW VANADIUM ARSENATES H2NC4H8NH2[(VIVO)2(HASO4)2(H2ASO4)2] AND H3NCH2CH2NH3[VIII(HASO4)2(H2ASO4)].H2O [J].

HAUSHALTER, RC ;

WANG, ZW ;

MEYER, LM ;

DHINGRA, SS ;

THOMPSON, ME ;

ZUBIETA, J .

CHEMISTRY OF MATERIALS, 1994, 6 (09) :1463-1464

[5] HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURES OF NACO3(PO4)(HPO4)2 AND NACO3(ASO4)(HASO4)2 - SYNTHETIC MODIFICATIONS OF THE MINERAL ALLUAUDITE [J].

LII, KH ;

SHIH, PF .

INORGANIC CHEMISTRY, 1994, 33 (14) :3028-3031

[6]

LII KH, 1994, J CHEM SOC DA, V7, P2289

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