THE SOLUTION STRUCTURE AND FLUXIONAL BEHAVIOR OF CYCLIC AND ACYCLIC (DIENE)FE(CO)2L COMPLEXES (L = PHOSPHINE, PHOSPHITE, ISONITRILE)

被引：26
作者：
HOWELL, JAS
WALTON, G
TIRVENGADUM, MC
SQUIBB, AD
PALIN, MG
MCARDLE, P
CUNNINGHAM, D
GOLDSCHMIDT, Z
GOTTLIEB, H
STRUL, G
机构：
[1] NATL UNIV IRELAND UNIV COLL GALWAY,DEPT CHEM,GALWAY,IRELAND
[2] BAR ILAN UNIV,DEPT CHEM,RAMAT GAN,ISRAEL
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 401卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(91)86199-Z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Variable temperature C-13 and P-31 NMR spectroscopy has been used to establish solution structures and conformer populations for a variety of cyclic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile). The solid state structures of (2,3-dimethylbutadiene)Fe(CO)2 PPh3 and (trans,trans-2,4-hexadiene)Fe(CO)2PPh3 have been determined and used as a basis for molecular modelling of steric effects in these complexes.
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页码：91 / 123
页数：33
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