STABLE GERMIRANE DERIVATIVES

被引：50
作者：
ANDO, W
OHGAKI, H
KABE, Y
机构：
[1] Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 06期
关键词：
D O I：
10.1002/anie.199406591
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electron‐rich and ‐poor olefins undergo addition reactions with germanediyl 1. Its reaction with hexatriene 2 gives 3; with N‐phenylmaleimide (4) the bicyclic germirane 5 is obtained. The two germirane products 3 and 5 were characterized by X‐ray structure analysis. R = (Me3Si)2CH. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码：659 / 661
页数：3
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