TRANSITION-METAL COMPLEXES OF DIAZENES .32. FUNCTIONALIZATION OF AROMATIC AZO-COMPOUNDS BY THE COBALT-CATALYZED, REGIOSELECTIVE DOUBLE ADDITION OF TOLANE - 2,6-DISTILBENYLAZOBENZENES AND 2,3-DIHYDROCINNOLINES

被引:84
作者
HALBRITTER, G [1 ]
KNOCH, F [1 ]
WOLSKI, A [1 ]
KISCH, H [1 ]
机构
[1] UNIV ERLANGEN NURNBERG,INST ANORGAN CHEM,D-91058 ERLANGEN,GERMANY
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 15-16期
关键词
D O I
10.1002/anie.199416031
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The substitution pattern determines whether distilbenylazobenzene compounds 1 or their subsequent products, the dihydrocinnolines 2, are isolated in the cobalt‐catalyzed solvent‐free reaction of azo compounds with diphenylacetylene. For several derivatives a photochromic equilibrium exists between the two forms. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码:1603 / 1605
页数:3
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