DIASTEREOSELECTIVE DIELS-ALDER REACTIONS BETWEEN SUBSTITUTED 1,3-BUTADIENES AND N-ALPHA-METHYLBENZYLMALEIMIDE

被引：34

作者：

BALDWIN, SW

GREENSPAN, P

ALAIMO, C

MCPHAIL, AT

机构：

[1] Department of Chemistry Duke University Durham

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 42期

关键词：

D O I：

10.1016/S0040-4039(00)79415-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The TiCl4 catalyzed reaction between 2-t-butyl-1,3-butadiene and N-alpha-methylbenzylmaleimide at -65-degrees-C affords diastereomeric Diels-Alder adducts in a 15:1 ratio. The structure of the major adduct was determined by x-ray.

引用

页码：5877 / 5880

页数：4

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