STUDY OF THE MICROSTRUCTURES OF PHENYL AND 4-FLUOROPHENYL POLYACRYLATES BY H-1 AND C-13 NMR-SPECTROSCOPY

被引：2

作者：

VAZQUEZ, B

GURRUCHAGA, M

GONI, I

NARVARTE, E

ROMAN, JS

机构：

[1] CSIC,INST CIENCIA & TECNOL POLIMEROS,E-28006 MADRID,SPAIN

[2] FAC QUIM SAN SEBASTIAN,DEPT CIENCIA & TECNOL POLIMEROS,E-20080 SAN SEBASTIAN,SPAIN

来源：

POLYMER | 1995年 / 36卷 / 18期

关键词：

POLYACRYLATES; MICROSTRUCTURE; NMR;

D O I：

10.1016/0032-3861(95)92017-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The microstructures of phenyl and 4-fluorophenyl polyacrylates were studied by 500 MHz H-1 and 125 MHz C-13 n.m.r. spectroscopy. The isotacticity parameters of both polyacrylates were calculated from the H-1 n.m.r. spectra, giving the values P-m = 0.44 for poly(phenyl acrylate) and P-m = 0.48 for poly(4-fluorophenyl acrylate). The C-13 n.m.r. spectra recorded in deuterated benzene showed well-resolved signals for carbonyl carbon, methine carbon and methylene carbon. The assignments were made on the basis of Bernoullian statistics, with good agreement between the experimental and calculated values for both polyacrylates.

引用

页码：3467 / 3472

页数：6

共 50 条

[41] Total assignment of the H-1 and C-13 NMR chemical shifts of three bisabolane hydrocarbons by 2D-NMR spectroscopy
Sy, LK
Brown, GD
MAGNETIC RESONANCE IN CHEMISTRY, 1997, 35 (06) : 424 - 425
[42] MICROSTRUCTURE DETERMINATION OF POLY(1-NAPHTHYLALKYL METHACRYLATE)S BY C-13 NMR-SPECTROSCOPY
RADIOTIS, T
SPYROS, A
DAIS, P
POLYMER, 1993, 34 (09) : 1846 - 1849
[43] ASSIGNMENTS OF THE H-1 AND C-13 NMR-SPECTRA OF TRANS-4-HYDROXY-N-9-FLUORENYLMETHOXYCARBONYL-L-PROLINE - USING ONE-DIMENSIONAL AND 2-DIMENSIONAL NMR-SPECTROSCOPY
AKSNES, DW
FRANCIS, GW
PAPAIOANNOU, D
MAGNETIC RESONANCE IN CHEMISTRY, 1993, 31 (09) : 876 - 877
[44] H-1 AND C-13 NMR ASSIGNMENT OF THEAFLAVIN, THEAFLAVIN MONOGALLATE AND THEAFLAVIN DIGALLATE
DAVIS, AL
CAI, Y
DAVIES, AP
MAGNETIC RESONANCE IN CHEMISTRY, 1995, 33 (07) : 549 - 552
[45] STRUCTURE OF A FERULOYLATED ARABINOXYLAN TETRASACCHARIDE THAT CONTAINS THE BETA-D-XYLP-(1 -] 2)-ALPHA-L-ARAF ELEMENT BY H-1 AND C-13 NMR-SPECTROSCOPY
HIMMELSBACH, DS
HARTLEY, RD
BORNEMAN, WS
POPPE, L
VANHALBEEK, H
MAGNETIC RESONANCE IN CHEMISTRY, 1994, 32 (03) : 158 - 165
[46] DETAILED MICROSTRUCTURAL ANALYSIS OF STYRENE METHACRYLONITRILE COPOLYMERS BY C-13 NMR-SPECTROSCOPY
DHAL, PK
STEIGEL, A
POLYMER, 1991, 32 (04) : 721 - 727
[47] A detailed H-1 and C-13 NMR study of a repeating disaccharide of hyaluronan: The effect of sodium and calcium ions
Sicinska, W
Lerner, LE
CARBOHYDRATE RESEARCH, 1996, 286 : 151 - 159
[48] GIAO Calculations of Chemical Shifts of NMR Spectra of H-1 and C-13 of the Hexahydroindoles Products
Benallou, Abdelilah
El Abdallaoui, Habib El Alaoui
Garmes, Hocine
MOROCCAN JOURNAL OF CHEMISTRY, 2015, 3 (02): : 238 - 248
[49] COMPLETE H-1 AND C-13 NMR SPECTRAL ASSIGNMENT OF PATCHOULENONE, A TRICYCLIC SESQUITERPENE KETONE
HISHAM, A
WRAY, V
PIETERS, L
CLAEYS, M
DOMMISSE, R
VLIETINCK, A
MAGNETIC RESONANCE IN CHEMISTRY, 1992, 30 (04) : 295 - 297
[50] Assignment of H-1 and C-13 NMR chemical shifts of nitroxanthones and development of additivity rules
Ibrom, W
Frahm, AW
MAGNETIC RESONANCE IN CHEMISTRY, 1996, 34 (11) : 937 - 944

← 1 2 3 4 5 →