SYNTHESIS OF CHIRAL AND C-2-SYMMETRICAL IRON(II) AND COBALT(II) COMPLEXES BEARING A NEW TETRADENTATE AMINE LIGAND SYSTEM

被引：41
作者：
RIEGER, B
ABUSURRAH, AS
FAWZI, R
STEIMAN, M
机构：
[1] Institut für Anorganische Chemie, Universität Tübingen, D-72076 Tübingen
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 497卷 / 1-2期
关键词：
IRON; COBALT; TETRADENTATE AMINE LIGAND; SOLID STATE STRUCTURES; CHIRALITY;
D O I：
10.1016/0022-328X(95)00119-B
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A synthesis for the new tetrapodal ligands [N,N'-dimethyl-N,N'-di(quinoline-2-methyl)]-1,2-ethylene diamine (L(1)) (3a) and [N,N'-di-benzyl-N,N'-di(quinoline-2-methyl)]-1,2 diamine (L(2)) (3b) and for the related octahedral complexes (L(1,2))FeCl2 (6a and 6b) and (L(1,2))CoCl2 (7a and 7b) is given. The solid state structures of 3b and 6a have been determined. Three different modes are possible for a tetradentate coordination of L(1,2) to FeCl2 or CoCl2. In 6a the ligand adopts a single chiral geometry around the Cl-Fe-Cl plane.
引用
收藏
页码：73 / 79
页数：7
相关论文
共 50 条
[21]   Iron(III), cobalt(II,III), copper(II) and zinc(II) complexes of 2-pyridineformamide 3-piperidylthiosemicarbazone [J].
Ketcham, KA ;
Swearingen, JK ;
Castiñeiras, A ;
Garcia, I ;
Bermejo, E ;
West, DX .
POLYHEDRON, 2001, 20 (28) :3265-3273
[22]   Synthesis and Characterisation of a New Schiff-Base-like Ligand and its Iron(II) Complexes [J].
Weber, Birgit ;
Obel, Jaroslava .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (15) :2474-2479
[23]   Synthesis and Anticancer Activity of Mixed Ligand, Cobalt (II), Nickel (II), Manganese (II) Complexes of Tertiary Diphosphines with Dithizone (H(2)dz) [J].
Mohamad, Hikmat Ali .
ORIENTAL JOURNAL OF CHEMISTRY, 2018, 34 (04) :1919-1925
[24]   Studies of artificial hydrolytic metalloenzymes: The catalyzed carboxyester hydrolysis by copper(II), zinc(II) and cobalt(II) complexes of the tripod ligand tris(2-benzimidazylmethyl)amine [J].
Xiangchen Yin ;
Chunchen Lin ;
Zhifen Zhou ;
Wandong Chen ;
Shourong Zhu ;
Huakuan Lin ;
Xuncheng Su ;
Yunti Chen .
Transition Metal Chemistry, 1999, 24 :537-540
[25]   Synthesis and mesomorphism of new chiral imines and copper(II) complexes [J].
Paul, Manoj K. ;
Kalita, Gayatri ;
Laskar, Atiqur Rahman ;
Choudhury, Trirup D. ;
Rao, Nandiraju V. S. .
JOURNAL OF MOLECULAR STRUCTURE, 2013, 1039 :219-226
[26]   Synthesis and magnetism of binuclear cobalt(II) complexes with the tetraacetylethene dianion as a bridging ligand [J].
Jingmin Shi ;
Jiqing Xu ;
Renzhang Wang ;
Guoyu Yang ;
Haoran Sun ;
Tiegang Wang ;
Peng Cheng ;
Daizheng Liao .
Transition Metal Chemistry, 1998, 23 :629-630
[27]   Organosilicon Amine Complexes of Cobalt(II), Cromium(III), and Neodymium(III): Synthesis and Properties [J].
V. V. Semenov ;
N. F. Cherepennikova ;
M. A. Lopatin ;
L. G. Klapshina ;
T. G. Mushtina ;
S. Ya. Khorshev ;
G. A. Domrachev ;
W. E. Douglas ;
B. A. Bushuk ;
A. I. Rubinov ;
S. B. Bushuk .
Russian Journal of Coordination Chemistry, 2002, 28 :394-406
[28]   Synthesis of four new vic-dioximes and their nickel(II), cobalt(II), copper(II) and cadmium(II) complexes [J].
Emine Özcan ;
Emin Karapınar ;
Baki Demirtaş .
Transition Metal Chemistry, 2002, 27 :557-561
[29]   Novel unsymmetrical tetradentate Schiff base complexes of cobalt (II) and palladium (II) with N2O2 donor sets [J].
Boghaei, DM ;
Mohebi, S .
JOURNAL OF CHEMICAL RESEARCH-S, 2001, (06) :224-226
[30]   Synthesis and Characterization of Two New Schiff Base Ligands and their Complexes with Cobalt(II), Nickel(II) and Copper(II) [J].
Ayşegül Yazicı ;
Filiz Akgün .
Transition Metal Chemistry, 2006, 31 :152-156
12345