FACILE PRODUCTION OF D-HISTIDINE BY ASYMMETRIC TRANSFORMATION OF L-HISTIDINE

被引：7
|
作者：
SHIRAIWA, T
SHINJO, K
MASUI, Y
OHTA, A
NATSUYAMA, H
MIYAZAKI, H
KUROKAWA, H
机构：
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 12期
关键词：
D O I：
10.1246/bcsj.64.3741
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An asymmetric transformation from L-histidine [L-His] to D-His was achieved by using salicylaldehyde as a catalyst for epimerization, and (2R, 3R)-tartaric acid as a resolving agent, in acetic acid. Treatment of the obtained salt with triethylamine in methanol gave D-His with 100% optical purity in 95% yield based on the starting L-His.
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页码：3741 / 3742
页数：2
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