ELECTROCHEMICAL PROPERTY AND FORMATION OF THE CATION RADICAL AND DICATION OF DINAPHTHO[1,8-B,C]-1,5-DITHIOCIN

被引：23

作者：

FUJIHARA, H

CHIU, JJ

FURUKAWA, N

机构：

来源：

CHEMISTRY LETTERS | 1990年 / 12期

关键词：

D O I：

10.1246/cl.1990.2217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new symmetrical dithio peri-bridged naphthalene, dinaphthol[1,8-b,c]-1,5-dithiocin (1) has been synthesized. The cyclic voltammogram of 1 showed one reversible oxidation peak. ESR spectrum of the concd H2SO4 solution of 1 showed the formation of the cation radical. The formation of the dictation of 1 was observed in the reaction of the corresponding monosulfoxide with concd D2SO4 by both high-field H-1 and C-13 NMR spectroscopy.

引用

页码：2217 / 2220

页数：4

共 14 条

[1] STRUCTURES OF THE RADICAL CATION AND DICATION FROM OXIDATION OF 1,6-DIAZABICYCLO[4.4.4]TETRADECANE
ALDER, RW
ORPEN, AG
WHITE, JM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (14) : 949 - 951
[2] ALDER RW, 1982, CHEM AMINO NITROSO N, pCH18
[3] STABILIZATION OF OXIDIZED SULFUR CENTERS IN ORGANIC SULFIDES - RADICAL CATIONS AND ODD-ELECTRON SULFUR-SULFUR BONDS
ASMUS, KD
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (12) : 436 - 442
[4] BARD AJ, 1976, ADV PHYSICAL ORGANIC, V13, P155
[5] BARRY G, 1966, B SOC CHIM FR, P2510
[6] TRANS-ANNULAR SULFUR-SULFUR INTERACTION IN 3,7,9-TRITHIABICYCLO[3.3.1]NONANE AS A NEW CYCLIC TRIS-SULFIDE - QUEST FOR THE INTRABRIDGED DITHIA DICATION
FUJIHARA, H
AKAISHI, R
FURUKAWA, N
[J]. TETRAHEDRON LETTERS, 1989, 30 (33) : 4399 - 4402
[7] 1,5-DISELENACYCLO-OCTANE - SYNTHESIS AND THE 1ST ISOLATION OF THE DISELENIDE PF6-SALT [R2SE+-SE+R2]
FUJIHARA, H
AKAISHI, R
ERATA, T
FURUKAWA, N
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (23) : 1789 - 1790
[8] FUJIHARA H, 1989, J MOL STRUC-THEOCHEM, V186, P261
[9] SULFUR SULFUR LONE PAIR AND SULFUR NAPHTHALENE INTERACTIONS IN NAPHTHO[1,8-B,C]-1,5-DITHIOCIN
GLASS, RS
ANDRUSKI, SW
BROEKER, JL
FIROUZABADI, H
STEFFEN, LK
WILSON, GS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) : 4036 - 4045
[10] SYNTHESIS OF SOME DIPHENYL AND TRIPHENYL DERIVATIVES OF ANTHRACENE AND NAPHTHALENE
HOUSE, HO
CAMPBELL, WJ
KOEPSELL, DG
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (07) : 1003 - &

← 1 2 →