TANDEM NORRISH TYPE-I REACTION AND INTRAMOLECULAR ARENE ALKENE META-PHOTOCYCLOADDITION - NOVEL PHOTOISOMERIZATION OF ARYL-SUBSTITUTED NORBORNAN-2-ONES TO TRIQUINANES

被引：15
作者：
DEKEUKELEIRE, D
HE, SL
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 05期
关键词：
D O I：
10.1039/c39920000419
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Irradiation of the aryl-substituted norbornan-2-ones 6 and 7 at 254 nm furnishes the triquinanes 16 and 17 (from 6) and 18 (from 7) via tandem Norrish Type I reaction and intramolecular arene-alkene meta-photocycloaddition of the intermediate unsaturated lactols 12 and 13, respectively.
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页码：419 / 420
页数：2
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