NEW CHEMICALLY PREPARED CONDUCTING PYRROLE BLACKS

被引：59

作者：

WALKER, JA

WARREN, LF

WITUCKI, EF

机构：

[1] Rockwell Int Science Cent, Thousand, Oaks, CA, USA, Rockwell Int Science Cent, Thousand Oaks, CA, USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1988年 / 26卷 / 05期

关键词：

IRON COMPOUNDS - Synthesis - ORGANIC COMPOUNDS - Electric Conductivity;

D O I：

10.1002/pola.1988.080260503

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of electrically conducting pyrrole 'black' polymers has been prepared by chemical oxidation of pyrrole with a variety of ferric salts. The synthesis and properties of these materials are described and compared with electrochemically-prepared analogs. Pyrrole 'blacks' with strong acid anion 'dopants' exhibited the highest conductivities, up to 62 OMEGA cm** minus **1 for the triflate-doped polymer. The adjustability and ease of synthesis of the ferric-derived polypyrroles render these particularly promising for large-scale processing of conducting polymers.

引用

页码：1285 / 1294

页数：10

共 20 条

[1] COMPARISON OF CARBON PASTE ELECTROCHEMISTRY OF POLYPYRROLES PREPARED BY CHEMICAL AND ELECTROCHEMICAL OXIDATION PATHS - SOME CHARACTERISTICS OF THE CHEMICALLY PREPARED POLYHALOPYRROLES [J].