Acyclic diene metathesis polymerization and precision polymers

被引：21
|
作者：
Sauty, Nicolas F. [1 ,2 ]
da Silva, Lucas Caire [1 ,2 ]
Schulz, Michael D. [1 ,2 ]
Few, Chip S. [1 ,2 ]
Wagener, Kenneth B. [1 ,2 ]
机构：
[1] Univ Florida, Dept Chem, George & Josephine Butler Polymer Res Lab, Gainesville, FL 32611 USA
[2] Univ Florida, Ctr Macromol Sci & Engn, Gainesville, FL 32611 USA
来源：
APPLIED PETROCHEMICAL RESEARCH | 2014年 / 4卷 / 02期
基金：
美国国家科学基金会;
关键词：
ADMET polymerization; Olefin metathesis; Precision polymers; Polyethylene;
D O I：
10.1007/s13203-014-0045-2
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The history of and major advances in the acyclic diene metathesis (ADMET) reaction are described. Because precise branch identity and frequency can be achieved by ADMET polymerizations of symmetrical alpha, omega-dienes, polyethylenes with precisely spaced alkyl branches of specified length have been prepared. Investigations of their morphologies and thermal properties have provided valuable insight into the behavior of polyethylene. ADMET preparation of ethylene copolymers and telechelic oligomers, as well as the properties of these materials, is also discussed.
引用
收藏
页码：225 / 233
页数：9
相关论文
共 50 条
  • [41] Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis (ADMET) Polymerization
    Song, Wei
    You, Yang
    Li, Tian-Jing
    Li, Juan
    Ding, Liang
    CHINESE JOURNAL OF POLYMER SCIENCE, 2018, 36 (06) : 703 - 711
  • [42] Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis(ADMET) Polymerization
    Wei Song
    Yang You
    Tian-Jing Li
    Juan Li
    Liang Ding
    Chinese Journal of Polymer Science, 2018, (06) : 703 - 711
  • [43] ACYCLIC DIENE METATHESIS (ADMET) OLIGOMERIZATION OF DIVINYLTETRAMETHYLDISILOXANE IN THE PRESENCE OF RHODIUM AND RUTHENIUM COMPLEXES
    MARCINIEC, B
    LEWANDOWSKI, M
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS, 1995, 5 (02): : 115 - 122
  • [44] Functional α,ω-dienes via thiol-Michael chemistry: synthesis, oxidative protection, acyclic diene metathesis (ADMET) polymerization and radical thiol-ene modification
    van Hensbergen, Johannes A.
    Gaines, Taylor W.
    Wagener, Kenneth B.
    Burford, Robert P.
    Lowe, Andrew B.
    POLYMER CHEMISTRY, 2014, 5 (21) : 6225 - 6235
  • [45] Functional precision polymers via ADMET polymerization
    Patricia R. Bachler
    Kenneth B. Wagener
    Monatshefte für Chemie - Chemical Monthly, 2015, 146 : 1053 - 1061
  • [46] Synthesis of new polyesters by acyclic diene metathesis polymerization of bio-based ,-dienes prepared from eugenol and castor oil (undecenoate)
    Duy Le
    Samart, Chanatip
    Kongparakul, Suwadee
    Nomura, Kotohiro
    RSC ADVANCES, 2019, 9 (18): : 10245 - 10252
  • [47] Post-Functionalization of Perfluorophenyl Ester-Functional Acyclic Diene Metathesis Polymer
    Daglar, Ozgun
    Durmaz, Hakan
    Hizal, Gurkan
    Tunca, Umit
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2016, 54 (16) : 2593 - 2598
  • [48] Synthesis of Phenylene Vinylene Macrocycles through Acyclic Diene Metathesis Macrocyclization and Their Aggregation Behavior
    Zhang, Chenxi
    Yu, Chao
    Long, Hai
    Denman, Ryan J.
    Jin, Yinghua
    Zhang, Wei
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (47) : 16935 - 16940
  • [49] Aliphatic-Aromatic Polyesters from Naturally Occurring Sinapic Acid through Acyclic-Diene Metathesis Polymerization in Bulk and Green Solvent Cyrene
    Zeaiter, Nour
    Fadlallah, Sami
    Flourat, Amandine L.
    Allais, Florent
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2022, 10 (51) : 17336 - 17345
  • [50] Designing Degradable Polymers from Tricycloalkenes via Complete Cascade Metathesis Polymerization
    Yang, Yongkang
    Cho, Yunhyeong
    Choi, Tae-Lim
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (18)
12345