Acyclic diene metathesis polymerization and precision polymers

被引：21
|
作者：
Sauty, Nicolas F. [1 ,2 ]
da Silva, Lucas Caire [1 ,2 ]
Schulz, Michael D. [1 ,2 ]
Few, Chip S. [1 ,2 ]
Wagener, Kenneth B. [1 ,2 ]
机构：
[1] Univ Florida, Dept Chem, George & Josephine Butler Polymer Res Lab, Gainesville, FL 32611 USA
[2] Univ Florida, Ctr Macromol Sci & Engn, Gainesville, FL 32611 USA
来源：
APPLIED PETROCHEMICAL RESEARCH | 2014年 / 4卷 / 02期
基金：
美国国家科学基金会;
关键词：
ADMET polymerization; Olefin metathesis; Precision polymers; Polyethylene;
D O I：
10.1007/s13203-014-0045-2
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The history of and major advances in the acyclic diene metathesis (ADMET) reaction are described. Because precise branch identity and frequency can be achieved by ADMET polymerizations of symmetrical alpha, omega-dienes, polyethylenes with precisely spaced alkyl branches of specified length have been prepared. Investigations of their morphologies and thermal properties have provided valuable insight into the behavior of polyethylene. ADMET preparation of ethylene copolymers and telechelic oligomers, as well as the properties of these materials, is also discussed.
引用
收藏
页码：225 / 233
页数：9
相关论文
共 50 条
  • [31] Synthesis of Precision Poly(1,3-adamantylene alkylene)s via Acyclic Diene Metathesis Polycondensation
    Friebel, Jonas
    Ender, Christopher P.
    Mezger, Markus
    Michels, Jasper
    Wagner, Manfred
    Wagener, Kenneth B.
    Weil, Tanja
    MACROMOLECULES, 2019, 52 (12) : 4483 - 4491
  • [32] Synthesis of Biobased Long-Chain Polyesters by Acyclic Diene Metathesis Polymerization and Tandem Hydrogenation and Depolymerization with Ethylene
    Nomura, Kotohiro
    Chaijaroen, Permpoon
    Abdellatif, Mohamed Mehawed
    ACS OMEGA, 2020, 5 (29): : 18301 - 18312
  • [33] Metal-containing Polymers Synthesized via Acyclic Diene Metathesis (ADMET) Polymerization Using Electrochemically-Reduced Tungsten-based Catalyst: Polycarbosilanes
    Solmaz Karabulut
    Cemil Aydogdu
    Bülent Düz
    Yavuz İmamoglu
    Journal of Inorganic and Organometallic Polymers and Materials, 2007, 17 : 517 - 523
  • [34] Metal-containing polymers synthesized via acyclic diene metathesis (ADMET) polymerization using electrochemically-reduced tungsten-based catalyst:: Polycarbosilanes
    Karabulut, Solmaz
    Aydogdu, Cemil
    Duz, Bulent
    Imamoglu, Yavuz
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2007, 17 (03) : 517 - 523
  • [35] Star-shaped polyphosphoesters with reactive end groups synthesized via acyclic diene metathesis polymerization and their transformation to nanostructures
    Ding, Liang
    Wei, Jun
    Qiu, Jun
    Wang, Jingjing
    Zhu, Zhenshu
    RSC ADVANCES, 2014, 4 (43): : 22342 - 22349
  • [36] Acyclic Triene Metathesis Polymerization with Chain-Stoppers: Molecular Weight Control in the Synthesis of Branched Polymers
    Fokou, Patrice A.
    Meier, Michael A. R.
    MACROMOLECULAR RAPID COMMUNICATIONS, 2008, 29 (19) : 1620 - 1625
  • [37] Ruthenium-Catalyzed Metathesis Reactions of ortho- and meta-Dialkenyl-Carboranes: Efficient Ring-Closing and Acyclic Diene Polymerization Reactions
    Guron, Marta
    Wei, Xiaolan
    Carroll, Patrick J.
    Sneddon, Larry G.
    INORGANIC CHEMISTRY, 2010, 49 (13) : 6139 - 6147
  • [38] One-pot Synthesis of End-functionalized Conjugated Polymers by Combined Acyclic Diene Metathesis (ADMET) Polymerization Using Molybdenum Catalyst with Wittig-type Coupling
    Miyashtta, Tomonari
    Inagaki, Akiko
    Nomura, Kotohiro
    JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 2016, 59 (05) : 197 - 203
  • [39] First Acyclic Diene Metathesis Polymerization Under Biphasic Conditions Using a Dicationic Ruthenium Alkylidene: Access to High-Molecular-Weight Polymers with Very Low Ruthenium Contamination
    Zhao, Jing
    Wang, Dongren
    Autenrieth, Benjamin
    Buchmeiser, Michael R.
    MACROMOLECULAR RAPID COMMUNICATIONS, 2015, 36 (02) : 190 - 194
  • [40] Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis (ADMET) Polymerization
    Wei Song
    Yang You
    Tian-Jing Li
    Juan Li
    Liang Ding
    Chinese Journal of Polymer Science, 2018, 36 : 703 - 711
12345