Acyclic diene metathesis polymerization and precision polymers

被引：21
|
作者：
Sauty, Nicolas F. [1 ,2 ]
da Silva, Lucas Caire [1 ,2 ]
Schulz, Michael D. [1 ,2 ]
Few, Chip S. [1 ,2 ]
Wagener, Kenneth B. [1 ,2 ]
机构：
[1] Univ Florida, Dept Chem, George & Josephine Butler Polymer Res Lab, Gainesville, FL 32611 USA
[2] Univ Florida, Ctr Macromol Sci & Engn, Gainesville, FL 32611 USA
来源：
APPLIED PETROCHEMICAL RESEARCH | 2014年 / 4卷 / 02期
基金：
美国国家科学基金会;
关键词：
ADMET polymerization; Olefin metathesis; Precision polymers; Polyethylene;
D O I：
10.1007/s13203-014-0045-2
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The history of and major advances in the acyclic diene metathesis (ADMET) reaction are described. Because precise branch identity and frequency can be achieved by ADMET polymerizations of symmetrical alpha, omega-dienes, polyethylenes with precisely spaced alkyl branches of specified length have been prepared. Investigations of their morphologies and thermal properties have provided valuable insight into the behavior of polyethylene. ADMET preparation of ethylene copolymers and telechelic oligomers, as well as the properties of these materials, is also discussed.
引用
收藏
页码：225 / 233
页数：9
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