THE EFFECT OF ULTRASOUND ON MASS-TRANSPORT TO A MICROELECTRODE

被引:49
作者
BIRKIN, PR
SILVAMARTINEZ, S
机构
关键词
D O I
10.1039/c39950001807
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ultrasonically generated cavitation events, and their subsequent asymmetrical collapse to form microjets directed at the solid-liquid interface, are observed by recording the electrochemical oxidation of ferrocene at gold microelectrodes irradiated with ultrasound.
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页码:1807 / 1808
页数:2
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共 22 条
[1]   UNIFORMLY ACCESSIBLE ELECTRODES [J].
ALBERY, WJ ;
BRUCKENSTEIN, S .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 144 (1-2) :105-112
[2]   HIGH SPEED CONTROLLED POTENTIAL COULOMETRY [J].
BARD, AJ .
ANALYTICAL CHEMISTRY, 1963, 35 (09) :1125-&
[3]   MODIFYING EFFECT OF ULTRASOUND UPON THE ELECTROCHEMICAL OXIDATION OF CYCLOHEXANECARBOXYLATE [J].
CHYLA, A ;
LORIMER, JP ;
MASON, TJ ;
SMITH, G ;
WALTON, DJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (09) :603-604
[4]   SONO-ELECTROCHEMISTRY - THE OXIDATION OF BIS(CYCLOPENTADIENYL)MOLYBDENUM DICHLORIDE [J].
COMPTON, RG ;
EKLUND, JC ;
PAGE, SD ;
REBBITT, TO .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (03) :389-393
[5]   VOLTAMMETRY IN THE PRESENCE OF ULTRASOUND - SONOVOLTAMMETRY AND SURFACE EFFECTS [J].
COMPTON, RG ;
EKLUND, JC ;
PAGE, SD ;
SANDERS, GHW ;
BOOTH, J .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (47) :12410-12414
[6]   THE TEMPERATURE OF CAVITATION [J].
FLINT, EB ;
SUSLICK, KS .
SCIENCE, 1991, 253 (5026) :1397-1399
[7]   COMPARISON OF HYDRODYNAMIC VOLTAMMETRY IMPLEMENTED BY SONICATION TO A ROTATING-DISK ELECTRODE [J].
HAGAN, CRS ;
COURY, LA .
ANALYTICAL CHEMISTRY, 1994, 66 (03) :399-405
[8]   SONOELECTROCHEMISTRY - EFFECTS OF ULTRASOUND ON VOLTAMMETRIC MEASUREMENTS AT A SOLID ELECTRODE [J].
KLIMA, J ;
BERNARD, C ;
DEGRAND, C .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 367 (1-2) :297-300
[9]   SONOCHEMISTRY .1. THE PHYSICAL ASPECTS [J].
LORIMER, JP ;
MASON, TJ .
CHEMICAL SOCIETY REVIEWS, 1987, 16 (02) :239-274
[10]   MICROJET ELECTRODE - A HYDRODYNAMIC ULTRAMICROELECTRODE WITH HIGH MASS-TRANSFER RATES [J].
MACPHERSON, JV ;
MARCAR, S ;
UNWIN, PR .
ANALYTICAL CHEMISTRY, 1994, 66 (13) :2175-2179