DECOMPOSITION OF CHLORINATED HYDROCARBONS USING METAL-OXIDES SUPPORTED ON CARBONACEOUS ADSORBENTS

被引：16
|
作者：
PETROSIUS, SC
DRAGO, RS
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 04期
关键词：
D O I：
10.1039/c39920000344
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of catalysts comprised of high-valent transition metal oxides supported in porous, carbonaceous adsorbents oxidize methylene chloride completely to CO, CO2 and HCl at 250-degrees-C and 1 atm; results with CD2Cl2 indicate that C-H bond dissociation is involved in the rate determining step of the reaction.
引用
收藏
页码：344 / 345
页数：2
相关论文
共 50 条
  • [41] ABSORPTION-SPECTRA OF METAL-OXIDES USING OPTOGALVANIC SPECTROSCOPY
    SCHENCK, PK
    MALLARD, WG
    TRAVIS, JC
    SMYTH, KC
    JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (11): : 5147 - 5150
  • [42] SUPPORTED TRANSITION-METALS AND METAL-OXIDES AS CATALYSTS FOR THE METAL-CARBONYL SUBSTITUTION-REACTION
    ALBERS, MO
    COVILLE, NJ
    SINGLETON, E
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 323 (01) : 37 - 52
  • [43] SUPPORTED METALS AND METAL-OXIDES AS PROMOTERS FOR THE METAL DIMER AND CLUSTER CATALYZED CO SUBSTITUTION-REACTION
    ALBERS, MO
    COVILLE, NJ
    SINGLETON, E
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 234 (01) : C13 - C15
  • [44] Catalytic decomposition of N2O using supported metal oxides.
    Jurczyk, K
    Drago, RS
    Kob, N
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 182 - COLL
  • [45] COMBINATION ANALYSIS OF METAL-OXIDES USING ESCA, AES, AND SIMS
    CONNER, GR
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1978, 15 (02): : 343 - 347
  • [46] ADSORPTIVE AND CATALYTIC PROPERTIES OF CO AND CO2 OVER SUPPORTED METAL-OXIDES
    RETHWISCH, DG
    DUMESIC, JA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 191 : 55 - COLL
  • [47] PHOTO-REDUCIBILITY OF SUPPORTED METAL-OXIDES AND LIFETIMES OF THEIR EXCITED TRIPLET-STATES
    ANPO, M
    TANAHASHI, I
    KUBOKAWA, Y
    JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (01): : 1 - 3
  • [48] LIQUID-PHASE OXIDATION OF P-XYLENE CATALYZED BY SUPPORTED METAL-OXIDES
    HRONEC, M
    MAJLING, J
    APPLIED CATALYSIS, 1987, 29 (01): : 67 - 71
  • [49] VALIDITY OF USING ISOPROPANOL DECOMPOSITION AS A TEST-REACTION FOR THE CHARACTERIZATION OF METAL-OXIDES BASICITY - COMPARISON WITH RESULTS OBTAINED FROM METHYLBUTYNOL DECOMPOSITION
    LAHOUSSE, C
    BACHELIER, J
    LAVALLEY, JC
    LAURONPERNOT, H
    LEGOVIC, AM
    JOURNAL OF MOLECULAR CATALYSIS, 1994, 87 (2-3): : 329 - 332
  • [50] REMOVAL OF NITROGEN-OXIDE WITH AMMONIA CATALYZED BY METAL-OXIDES, SUPPORTED BY NATURAL ZEOLITE
    FUJITA, N
    MATSUURA, C
    TAMURA, T
    OSHIMA, K
    ITO, W
    NEGISHI, N
    NIPPON KAGAKU KAISHI, 1977, (05) : 722 - 728
12345