DECOMPOSITION OF DIHYDROARTEMISITENE ON SILICA-GEL

被引：15

作者：

ELFERALY, FS ^{[1
]}

AYALP, A ^{[1
]}

ALYAHYA, MA ^{[1
]}

MCPHAIL, DR ^{[1
]}

MCPHAIL, AT ^{[1
]}

机构：

[1] DUKE UNIV,PAUL M GROSS CHEM LAB,DEPT CHEM,DURHAM,NC 27706

来源：

JOURNAL OF NATURAL PRODUCTS | 1990年 / 53卷 / 04期

关键词：

D O I：

10.1021/np50070a020

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Dihydroartemisitene [5], obtained by reducing its hydroperoxy analogue with triphenylphosphine, was found to undergo isomerization to the keto-aldehyde 6 when chromatographed on Si gel. X-ray crystallographic analysis established the structure of each compound. © 1990, American Chemical Society. All rights reserved.

引用

页码：920 / 925

页数：6

共 6 条

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QUINOA, E ;

KHO, E ;

MANES, LV ;

CREWS, P ;

BAKUS, GJ .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (22) :4260-4264

[3] ANTITUMOR CYCLIC PEROXIDES FROM THE SPONGE PLAKORTIS-LITA [J].

SAKEMI, S ;

HIGA, T ;

ANTHONI, U ;

CHRISTOPHERSEN, C .

TETRAHEDRON, 1987, 43 (01) :263-268

[4]

SILVERSTEIN RM, 1981, SPECTROMETRIC IDENTI, P263

[5]

SILVERSTEIN RM, 1981, SPECTROMETRIC IDENTI, P225

[6]

WELLS RJ, 1976, TETRAHEDRON LETT, P2637

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