DECOMPOSITION OF DIHYDROARTEMISITENE ON SILICA-GEL

被引:14
|
作者
ELFERALY, FS [1 ]
AYALP, A [1 ]
ALYAHYA, MA [1 ]
MCPHAIL, DR [1 ]
MCPHAIL, AT [1 ]
机构
[1] DUKE UNIV,PAUL M GROSS CHEM LAB,DEPT CHEM,DURHAM,NC 27706
来源
JOURNAL OF NATURAL PRODUCTS | 1990年 / 53卷 / 04期
关键词
D O I
10.1021/np50070a020
中图分类号
Q94 [植物学];
学科分类号
071001 ;
摘要
Dihydroartemisitene [5], obtained by reducing its hydroperoxy analogue with triphenylphosphine, was found to undergo isomerization to the keto-aldehyde 6 when chromatographed on Si gel. X-ray crystallographic analysis established the structure of each compound. © 1990, American Chemical Society. All rights reserved.
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页码:920 / 925
页数:6
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