2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP) - A NEW ATROPISOMERIC BIS(TRIARYL)PHOSPHINE - SYNTHESIS AND ITS USE IN THE RH(I)-CATALYZED ASYMMETRIC HYDROGENATION OF ALPHA-(ACYLAMINO)ACRYLIC ACIDS

被引：299

作者：

MIYASHITA, A

TAKAYA, H

SOUCHI, T

NOYORI, R

机构：

[1] OKAZAKI NATL RES INST,CTR CHEM MAT,INST MOLEC SCI,OKAZAKI 444,JAPAN

[2] NAGOYA UNIV,DEPT CHEM,NAGOYA,AICHI 464,JAPAN

来源：

TETRAHEDRON | 1984年 / 40卷 / 08期

关键词：

D O I：

10.1016/S0040-4020(01)82411-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：1245 / 1253

页数：9

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[23] ASYMMETRIC HYDROGENATION OF PROCHIRAL CARBOXYLIC-ACIDS CATALYZED BY THE 5-COORDINATE RUTHENIUM(II)-HYDRIDE COMPLEX [RUH(BINAP)2]PF6 (BINAP=(R)-OR (S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL) [J].

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[24] Intense fluorescence of metal-to-ligand charge transfer in [Pt(0)(binap)2] [binap=2,2'-bis(diphenylphosphino)-1,1'-binaphthyl] [J].

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[27] Trinuclear clusters of osmium containing monodentate, chelating and orthometallated forms of 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl (BINAP) [J].

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[28] Kinetics and mechanism of catalysis of the asymmetric hydrogenation of α,β-unsaturated carboxylic acids by Bis(carboxylato){2,2 prime -bis(diphenylphosphino)-1, 1 prime -binaphthyl}ruthenium-(II), [RuII(BINAP)(O2CR)2] [J].

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[29] Facile and practical synthesis of (R)-6-Br-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl [J].

Yuan, XY ;

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SYNTHETIC COMMUNICATIONS, 2006, 36 (08) :1057-1062

[30] SYNTHESIS OF (R)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2'-DIMETHOXY-1,1'-BINAPTHYL AND (S)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2'-DIMETHOXY-1,1'-BINAPHTHYL, A NEW AXIALLY DISSYMMETRIC BIS(TRIARYLPHOSPHINE) [J].

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