ON THE SCREENING OF HYDRODYNAMIC INTERACTIONS IN DILUTE POLYMER-SOLUTIONS

被引:5
|
作者
MUTHUKUMAR, M
机构
[1] Univ of Massachusetts, United States
关键词
Hydrodynamics - Relaxation Processes;
D O I
10.1021/ma00187a041
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The authors show that the errors in the work of Y. Shiwa et al. originate from the inconsistent use of formulas for different regimes. For specificity, the authors consider the concentration dependence of the relaxation time (τp) of the pth normal mode of polymer chains in dilute solutions. The initial concentration dependence of τp for linear flexible chains in three dimensions was derived. Since the internal modes of the chain are of concern, the characteristic length scale is shorter than the size of the polymer chain.
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页码:2891 / 2892
页数:2
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