CO2(CO)8-CATALYZED RING-OPENING CARBONYLATION OF CYCLIC ETHERS USING N-SILYLAMINES

被引：19

作者：

WATANABE, Y

NISHIYAMA, K

ZHANG, K

OKUDA, F

KONDO, T

TSUJI, Y

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 03期

关键词：

D O I：

10.1246/bcsj.67.879

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Co2(CO)8-catalyzed ring-opening carbonylation of oxiranes and oxetane smoothly proceeds with high regioselectivity under 1 atm of carbon monoxide at room temperature to give the corresponding beta- and gamma-siloxy amides in high yields, respectively. [(R3Si)2NR1R2]+[Co-(CO)4]- is thought to be an active catalyst species and directs the high regioselectivity of the carbonylation.

引用

页码：879 / 882

页数：4

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