STRUCTURE OF [1-(3,5-DIMETHYL-1-PYRAZOLYL)-3-THIAPENTANE-N,S]-BIS(NITRATO-0,0)COPPER(II)

被引：2
|
作者：
HAANSTRA, WG [1 ]
DRIESSEN, WL [1 ]
REEDIJK, J [1 ]
机构：
[1] LEIDEN UNIV,GORLAEUS LABS,POB 9502,2300 RA LEIDEN,NETHERLANDS
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷
关键词：
D O I：
10.1107/S0108270191009204
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[Cu(C9H16N2S)(NO3)2], M(r) = 371.9, orthorhombic, Pca2(1), a = 11.55 (1), b = 7.877 (2), c = 16.866 (5) angstrom, V = 1534 angstrom 3, Z = 4, D(x) = 1.6 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 16 cm-1, F(000) = 764, T = 298 K, R = 0.026 and wR = 0.040 for 1507 observed reflections [I > 2-sigma(I)]. The structure of this compound consists of a copper(II) ion coordinated by one pyrazole nitrogen [1.943 (4) angstrom], one thioether sulfur [2.332 (1) angstrom] and two monodentate nitrate anions [1.979 (4) and 2.021 (3) angstrom]. The basic coordination geometry is square planar with the nitrates in cis positions. The orientation of the nitrates results in semi coordination of two additional nitrate oxygen atoms at 2.411 (4) and 2.479 (4) angstrom. The so-defined coordination geometry is a severely distorted octahedron.
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页码：14 / 16
页数：3
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