OXIDATION OF BUCKMINSTERFULLERENE C-60 IN BRONSTED ACIDS

被引：8
|
作者：
SCHARFF, P
BISCHOF, W
EBINAL, S
EHRHARDT, C
GERKEN, R
KAISER, V
MENZEL, F
TANKE, C
机构：
[1] Institut für Anorganische und Analytische Chemie, TU Clausthal, D-38670 Clausthal-Zellerfeld
来源：
CARBON | 1994年 / 32卷 / 04期
关键词：
FULLERENE; C-60; REDOX PROPERTIES; C-60 DERIVATIVES WITH ACIDS; VIBRATIONAL SPECTROSCOPY; ESR; THERMOGRAVIMETRY;
D O I：
10.1016/0008-6223(94)90093-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
C60 fullerene derivatives with H2SO4 (brown), HNO3 (light orange), and HClO4 (light brown) were prepared both by chemical and electrochemical oxidation of C60 in 97% H2SO4, fuming H2SO4, 65% HNO3, fuming HNO3, and 70% HClO4, respectively. A yellow-orange derivative was obtained by reacting the C60 fullerene with N2O5. In the case of the H2SO4 derivatives, the soccer ball structure of the C60 molecules proved to be maintained, whereas in the products obtained with HNO3, HClO4, and N2O5, the structure is different.
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页码：709 / 714
页数：6
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