NATURAL-GAS HYDRATE PHASE-EQUILIBRIA AND KINETICS - UNDERSTANDING THE STATE-OF-THE-ART

被引：24

作者：

SLOAN, ED

机构：

[1] Chem Eng & Petroleum Refining Dept, Golden

来源：

REVUE DE L INSTITUT FRANCAIS DU PETROLE | 1990年 / 45卷 / 02期

关键词：

D O I：

10.2516/ogst:1990018

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

An overview is given of gas hydrate phase equilibria and kinetics. It is suggested that with only a few exceptions hydrate phase equilibrium conditions may be predicted with acceptable accuracy for industrial purpose via the current state-of-the-art. Hydrate research is at a milestone, going beyond equilibrium experiments to time-dependent measurements, such as in the kinetic arena, where there is a severe paucity of data. To illustrate the concepts, two qualitative microscopic models are presented: 1) the hydrate guest: cavity size ratio and 2) the dissolution of apolar molecules in liquid water. Hypotheses for macroscopic phase equilibria and kinetic nucleation phenomena are given, based upon the two models. -Author

引用

页码：245 / 266

页数：22

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