THE 3-NU(1)+NU(3) VIBRATIONAL OVERTONE SPECTRUM OF (CH4)-C-13

被引：8
作者：
BORAAS, K
REILLY, JP
机构：
[1] Department of Chemistry, Indiana University, Bloomington, IN
来源：
CHEMICAL PHYSICS | 1995年 / 190卷 / 2-3期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0301-0104(94)00314-Z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The 3 nu(1) + nu(3) vibrational overtone spectrum of (CH4)-C-13 is recorded under Doppler-limited resolution conditions using a titanium sapphire laser-based photoacoustic spectrometer. Data at two temperatures, 100 and 293 K, are presented. The observed spectral congestion is qualitatively similar to that observed for (CH4)-C-12, but the detailed re-vibrational structure of the two isotope variants is completely different. The data reflect the complicating influences of tetrahedral fine structure and vibrational state mixing.
引用
收藏
页码：301 / 309
页数：9
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