STEREOSPECIFIC GAMMA-RAY-INDUCED TRIMERIZATION OF CRYSTALLINE-SODIUM TRANS-2-BUTENOATE

被引：30
作者：
DEDELGADO, GCD [1 ]
WHEELER, KA [1 ]
SNIDER, BB [1 ]
FOXMAN, BM [1 ]
机构：
[1] BRANDEIS UNIV, DEPT CHEM, POB 9110, WALTHAM, MA 02254 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1991年 / 30卷 / 04期
关键词：
D O I：
10.1002/anie.199104201
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Only one of eight possible diastereomers of the sodium salt of the tricarboxylic acid 1 is formed in high yield in the novel title reaction. Compound 1 cannot be prepared in solution, by thermolysis or by UV irradiation of crystalline sodium trans‐2‐butenoate. The trimerization is interesting as a model reaction for the early stages of oligomer formation in a solid‐state polymerization reaction. (Figure Presented.) Copyright © 1991 by VCH Verlagsgesellschaft mbH, Germany
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页码：420 / 422
页数：3
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