STEREOSPECIFIC GAMMA-RAY-INDUCED TRIMERIZATION OF CRYSTALLINE-SODIUM TRANS-2-BUTENOATE

被引：30

作者：

DEDELGADO, GCD ^{[1
]}

WHEELER, KA ^{[1
]}

SNIDER, BB ^{[1
]}

FOXMAN, BM ^{[1
]}

机构：

[1] BRANDEIS UNIV, DEPT CHEM, POB 9110, WALTHAM, MA 02254 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1991年 / 30卷 / 04期

关键词：

D O I：

10.1002/anie.199104201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Only one of eight possible diastereomers of the sodium salt of the tricarboxylic acid 1 is formed in high yield in the novel title reaction. Compound 1 cannot be prepared in solution, by thermolysis or by UV irradiation of crystalline sodium trans‐2‐butenoate. The trimerization is interesting as a model reaction for the early stages of oligomer formation in a solid‐state polymerization reaction. (Figure Presented.) Copyright © 1991 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：420 / 422

页数：3

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