PALLADIUM-CATALYZED COUPLING OF ARYL IODIDES, NONCONJUGATED DIENES, AND CARBON NUCLEOPHILES BY PALLADIUM MIGRATION

被引：72

作者：

LAROCK, RC ^{[1
]}

LU, YD ^{[1
]}

BAIN, AC ^{[1
]}

RUSSELL, CE ^{[1
]}

机构：

[1] MUHLENBERG COLL,DEPT CHEM,ALLENTOWN,PA 18104

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 15期

关键词：

D O I：

10.1021/jo00015a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl iodides, nonconjugated dienes, and carbon nucleophiles react in the presence of a palladium catalyst to give good yields of coupled products apparently formed by arylpalladium generation and addition to the less substituted end of the diene, palladium migration down the carbon chain to form a pi-allylpalladium intermediate, and carbanion displacement of the palladium moiety.

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收藏

页码：4589 / 4590

页数：2

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