THE MECHANISTIC ROLE OF ETA-2-VINYL COMPLEXES IN METAL-PROMOTED ALKYNE OLIGOMERIZATIONS - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [W(ETA-5-C(CF3)=C(CF3)C(CO2ME)=C(CO2ME)C(CF3)=C(CF3)SPRI)(ETA-5-C5H5)], [WF(ETA-5-C(=CF2)C(CF3)=C(CO2ME)C(CO2ME)C(CF3)C(CF3)SPRI)(ETA-5-C5H5)], AND [W(ETA-4-C(CF3)C(CF3)=C(ME)C(ME)SPRI)(ETA-2-CF3C=CCF3)(ETA-5-C5H5)])

被引：49

作者：

CARLTON, L

DAVIDSON, JL

EWING, P

MANOJLOVICMUIR, L

MUIR, KW

机构：

[1] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND

[2] UNIV GLASGOW,DEPT MED,GLASGOW G12 8QQ,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1985年 / 21期

关键词：

D O I：

10.1039/c39850001474

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1474 / 1476

页数：3

共 11 条

[1] STEREOCHEMICAL CONTROL OF ALKYNE OLIGOMERIZATION AT A DIRUTHENIUM CENTER - X-RAY STRUCTURES OF [RU2(CO)(MU-CO)(MU-C4H4CME2)(ETA-C5H5)2] AND [RU2(MU-CO)[MU-C4(CO2ME)4CH2](ETA-C5H5)2] [J].

ADAMS, PQ ;

DAVIES, DL ;

DYKE, AF ;

KNOX, SAR ;

MEAD, KA ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (05) :222-224

[2] REACTIONS OF COORDINATED LIGANDS .33. MONONUCLEAR ETA-2-VINYL COMPLEXES - SYNTHESIS, STRUCTURE, AND REACTIVITY [J].

ALLEN, SR ;

BEEVOR, RG ;

GREEN, M ;

NORMAN, NC ;

ORPEN, AG ;

WILLIAMS, ID .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (03) :435-450

[3] CARBON-HYDROGEN-TRANSITION METAL BONDS [J].

BROOKHART, M ;

GREEN, MLH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) :395-408

[4] REVERSIBLE MIGRATION OF A COORDINATED MERCAPTO LIGAND ON TO A METAL-BOUND ALKYNE TO GIVE ETA-2-VINYL COMPLEXES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [WC(CF3).C(CF3)SPRI(CF3C=CCF3)(ETA-5-C5H5)] [J].

CARLTON, L ;

DAVIDSON, JL ;

MILLER, JC ;

MUIR, KW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (01) :11-13

[5] MECHANISM OF ZIEGLER-NATTA POLYMERIZATION OF ACETYLENE - A NUTATION NMR-STUDY [J].

CLARKE, TC ;

YANNONI, CS ;

KATZ, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (26) :7787-7789

[6] REACTION OF CATIONIC CYCLOBUTADIENERUTHENIUM COMPLEXES WITH HYDRIDE ANION DONORS - EVIDENCE FOR THE FORMATION OF ETA-4 (5E) BUTADIENYL SPECIES AND FRAGMENTATION OF THE CYCLOBUTADIENE RING - CRYSTAL-STRUCTURES OF [RU=C(PH)-ETA-3-(C(PH).CH(PH).CH(PH))-(ETA-C5H5)] AND [RU2(ETA-CO)(ETA-(Z)-C(PH)=CH(PH))(CO)2(ETA-4-C4PH4)(ETA-C5H5)]ON [J].

CROCKER, M ;

GREEN, M ;

ORPEN, AG ;

NEUMANN, HP ;

SCHAVERIEN, CJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (20) :1351-1353

[7] ISOMERISM AND FLUXIONAL BEHAVIOR IN ETA-2-VINYL COMPLEXES RESULTING IN INVERSION OF CONFIGURATION AT AN ASYMMETRIC CARBON-ATOM - THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2 ISOMERIC FORMS OF [MOCL[ETA-2-C(CF3)C(CF3)(PET3)](CF3C=CCF3)(ETA-5-C5H5)] [J].

DAVIDSON, JL ;

WILSON, WF ;

MANOJLOVICMUIR, L ;

MUIR, KW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 254 (01) :C6-C10

[8] THE MECHANISM OF METAL-PROMOTED ALKYNE CYCLO-OLIGOMERIZATION WITH ISOCYANIDES LEADING TO CYCLOPENTADIENE DERIVATIVES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [WSPRI(CNBUT)(ETA-2-C4(CF3)4CNBUT)(ETA-5-C5H5)] CONTAINING AN ETA-2-TETRAKIS(TRIFLUOROMETHYL)CYCLOPENTADIENIMINE LIGAND [J].

DAVIDSON, JL ;

WILSON, WF ;

MUIR, KW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (08) :460-462

[9] CO-ORDINATIVELY UNSATURATED ACETYLENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN - REACTIONS OF [MCL(CF3C'CCF3)2(ETA-5-C5H5)] (M = MO OR W) WITH OCTACARBONYLDICOBALT LEADING TO BINUCLEAR METALLACYCLOPENTADIENE COMPLEXES [J].

DAVIDSON, JL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (08) :1667-1670

[10] INITIATION OF ACETYLENE POLYMERIZATION BY METAL CARBENES [J].

KATZ, TJ ;

LEE, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (01) :422-424

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