C-13 NMR ANALYSIS OF PROPENE BUTENE COPOLYMER - STERIC STRUCTURE OF CHAIN END GROUPS AND INHOMOGENEITY OF ISOTACTIC SITES

被引：16
作者：
LOCATELLI, P
SACCHI, MC
TRITTO, I
FORLINI, F
机构：
[1] Istituto di Chimica delle Macromolecole del CNR, Via E. Bassini, 15
来源：
MACROMOLECULES | 1990年 / 23卷 / 08期
关键词：
D O I：
10.1021/ma00210a045
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Propene and 1-butene have been copolymerized in the presence of the catalytic system TiCl3/ A1(13CH2CH3)3. The results of13C NMR analysis of chain end groups in isotactic fractions of different composition provide stereochemical evidences of the inhomogeneity of the isotactic sites. © 1990, American Chemical Society. All rights reserved.
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页码：2406 / 2409
页数：4
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