C-13 NMR ANALYSIS OF PROPENE BUTENE COPOLYMER - STERIC STRUCTURE OF CHAIN END GROUPS AND INHOMOGENEITY OF ISOTACTIC SITES

被引：16

作者：

LOCATELLI, P

SACCHI, MC

TRITTO, I

FORLINI, F

机构：

[1] Istituto di Chimica delle Macromolecole del CNR, Via E. Bassini, 15

来源：

MACROMOLECULES | 1990年 / 23卷 / 08期

关键词：

D O I：

10.1021/ma00210a045

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Propene and 1-butene have been copolymerized in the presence of the catalytic system TiCl3/ A1(13CH2CH3)3. The results of13C NMR analysis of chain end groups in isotactic fractions of different composition provide stereochemical evidences of the inhomogeneity of the isotactic sites. © 1990, American Chemical Society. All rights reserved.

引用

页码：2406 / 2409

页数：4

共 14 条

[1] C-13 NMR ANALYSIS OF PROPYLENE-BUTYLENE CO-POLYMERS BY A REACTION PROBABILITY MODEL [J].