A CRYSTALLOGRAPHIC MAP OF CHIRAL RECOGNITION IN PI-COMPLEXES OF AROMATIC-ALDEHYDES AND A CHIRAL TRANSITION-METAL LEWIS-ACID - ENANTIOFACE BINDING SELECTIVITIES IN SOLUTION CORRELATE TO DISTANCES BETWEEN METAL AND CARBON STEREOCENTERS IN THE SOLID-STATE

被引：7

作者：

BOONE, BJ ^{[1
]}

KLEIN, DP ^{[1
]}

MENDEZ, NQ ^{[1
]}

SEYLER, JW ^{[1
]}

ARIF, AM ^{[1
]}

GLADYSZ, JA ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 02期

关键词：

D O I：

10.1039/c39950000279

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title claim is established with five pi-aromatic aldehyde complexes [(eta(5)-C5H5)Re(NO)(PPh(3))(eta(2)-O=CHAr)](+) X(-); electronegative aryl substituents give shorter rhenium-carbon bond lengths and higher binding selectivities, providing the first easily conceptualized mechanism for an electronic effect upon chiral recognition.

引用

页码：279 / 281

页数：3

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