ON THE CORRELATION BETWEEN THE H-1-NMR CHEMICAL-SHIFT AND THE STRETCHING VIBRATION FREQUENCY OF HYDROXYL-GROUPS IN SOLIDS

被引：59

作者：

BRUNNER, E ^{[1
]}

KARGE, HG ^{[1
]}

PFEIFER, H ^{[1
]}

机构：

[1] MAX PLANCK GESELL,FRITZ HABER INST,W-1000 BERLIN 33,GERMANY

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 1992年 / 176卷

关键词：

HYDROXYL GROUPS; H-1 NMR CHEMICAL SHIFT; STRETCHING VIBRATION FREQUENCY; CORRELATION;

D O I：

10.1524/zpch.1992.176.Part_2.173

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A clear correlation between the H-1 NMR chemical shift and the stretching vibration frequency of hydroxyl groups in solids could be stated. Surface hydroxyl groups in zeolites and related materials have been taken into account as well as water molecules in solid hydrates and strongly hydrogen-bonded protons in inorganic solids. Cationic hydroxyl groups in zeolites (CaOH, MgOH) as well as CaOH groups in calcium phosphates differ significantly from the correlation found for the above-mentioned types of hydroxyls.

引用

页码：173 / 183

页数：11

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