THE VACUUM ULTRAVIOLET-SPECTRUM OF [MN2(CO)10]

被引：7
作者：
MARQUEZ, A
SANZ, JF
GELIZE, M
DARGELOS, A
机构：
[1] UNIV SEVILLA,FAC CHEM,DEPT PHYS CHEM,E-41012 SEVILLE,SPAIN
[2] FAC SCI PAU,CHIM STRUCT LAB,F-64000 PAU,FRANCE
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 434卷 / 02期
关键词：
D O I：
10.1016/0022-328X(92)83308-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The vacuum ultraviolet electronic spectrum of [Mn2(CO)10] in the gas phase at 40-degrees-C has been recorded in the 210-110 nm region. The spectrum shows a set of three broad bands, poorly resolved. The first band appears at approximately 50000 cm-1 and lies in the classical UV region, thus being responsible for the strong absorption observed in the limit of the UV spectrum. A second extremly intense band system centred at about 70000 cm-1 dominates the region of high energy.
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页码：235 / 240
页数：6
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