A NEW RING EXPANSION APPROACH TO 3-FORMYL-2-CYCLOHEPTEN-1-ONES

被引：6

作者：

GUERRERO, A

PARRILLA, A

CAMPS, F

机构：

[1] Department of Biological Organic Chemistry, C.I.D. (CSIC) Jordi Girona Salgado

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 13期

关键词：

D O I：

10.1016/S0040-4039(00)98808-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction off non-enolizable 2-n-butylthiomethylene cyclohexanones with methoxy (phenylthio)methyllithium, followed by hydrolysis off the diastereomeric mixture off resulting alcohols, provides a new and efficient ring enlargement reaction for the synthesis of the previously unreported 3-formyl-2-cyclohepten-1-ones. © 1990 Pergamon Press plc.

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页码：1873 / 1876

页数：4

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